Mahy, W, Plucinski, P, Jover, J & Frost, CG 2015,
‘Ruthenium-catalyzed O- to S-alkyl migration: a pseudoreversible Barton-McCombie pathway’ <em>Angewandte Chemie-International Edition</em>, vol 54, no. 37, pp. 10944-10948.
Abstract
AbstractA practical ruthenium‐catalyzed O‐ to S‐alkyl migration affords structurally diverse thiooxazolidinones in excellent yields. Our studies suggest this catalytic transformation proceeds through a pseudoreversible radical pathway drawing mechanistic parallels to the classic Barton–McCombie reaction.
